One hundred years of mountain hydrology in Switzerland by the WSL     

Christoph Hegg  Brian W. McArdell  Alexandre Badoux 《水文研究》2006,20(2):371-376

In 1903 the Swiss Federal Research Institute WSL started its first forest hydrology measurements with the aim to deliver a sound scientific basis for the implementation of new forest legislation introduced in Switzerland in 1876. This legislation was triggered by several large floods that occurred in Switzerland, for which a major cause was widely seen as the poor condition of forests at that time. Consequently, hydrologic research at WSL first focused on the influence of forests on floods. In the second half of the 20th century, other hydrological issues such as water quality, snow hydrology and sediment transport complemented the hydrologic research at WSL. Some recent results of this work are presented in three papers joining this introductory paper to mark the 100th anniversary of hydrologic research at WSL. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Solar hard X-ray bursts   总被引：3，自引：0，他引：3  

Brian R. Dennis 《Solar physics》1985,100(1-2):465-490

The major results from SMM are presented as they relate to our understanding of the energy release and particle transportation processes that lead to the high-energy X-ray aspects of solar flares. Evidence is reviewed for a 152–158 day periodicity in various aspects of solar activity including the rate of occurrence of hard X-ray and gamma-ray flares. The statistical properties of over 7000 hard X-ray flares detected with the Hard X-Ray Burst Spectrometer are presented including the spectrum of peak rates and the distribution of the photon number spectrum. A flare classification scheme introduced by Tanaka is used to divide flares into three different types. Type A flares have purely thermal, compact sources with very steep hard X-ray spectra. Type B flares are impulsive bursts which show double footpoints in hard X-rays, and soft-hard-soft spectral evolution. Type C flares have gradually varying hard X-ray and microwave fluxes from high altitudes and show hardening of the X-ray spectrum through the peak and on the decay. SMM data are presented for examples of type B and type C events. New results are presented showing coincident hard X-rays, O v, and UV continuum observations in type B events with a time resolution of 128 ms. The subsecond variations in the hard X-ray flux during 10% of the stronger events are discussed and the fastest observed variation in a time of 20 ms is presented. The properties of type C flares are presented as determined primarily from the non-imaged hard X-ray and microwave spectral data. A model based on the association of type C flares and coronal mass ejections is presented to explain many of the characteristics of these gradual flares.  相似文献   

Time scale of an early to mid-Paleozoic orogenic cycle of the long-lived Central Asian Orogenic Belt, Inner Mongolia of China: Implications for continental growth   总被引：50，自引：0，他引：50  

Ping Jian  Dunyi Liu  Alfred Krner  Brian F. Windley  Yuruo Shi  Fuqin Zhang  Guanghai Shi  Laicheng Miao  Wei Zhang  Qi Zhang  Liqao Zhang  Jishun Ren 《Lithos》2008,101(3-4):233-259

We present a detailed, new time scale for an orogenic cycle (oceanic accretion–subduction–collision) that provides significant insights into Paleozoic continental growth processes in the southeastern segment of the long-lived Central Asian Orogenic Belt (CAOB). The most prominent tectonic feature in Inner Mongolia is the association of paired orogens. A southern orogen forms a typical arc-trench complex, in which a supra-subduction zone ophiolite records successive phases during its life cycle: birth (ca. 497–477 Ma), when the ocean floor of the ophiolite was formed; (2) youth (ca. 473–470 Ma), characterized by mantle wedge magmatism; (3) shortly after maturity (ca. 461–450 Ma), high-Mg adakite and adakite were produced by slab melting and subsequent interaction of the melt with the mantle wedge; (4) death, caused by subduction of a ridge crest (ca. 451–434 Ma) and by ridge collision with the ophiolite (ca. 428–423 Ma). The evolution of the magmatic arc exhibits three major coherent phases: arc volcanism (ca. 488–444 Ma); adakite plutonism (ca. 448–438 Ma) and collision (ca. 419–415 Ma) of the arc with a passive continental margin. The northern orogen, a product of ridge-trench interaction, evolved progressively from coeval generation of near-trench plutons (ca. 498–461 Ma) and juvenile arc crust (ca. 484–469 Ma), to ridge subduction (ca. 440–434 Ma), microcontinent accretion (ca. 430–420 Ma), and finally to forearc formation. The paired orogens followed a consistent progression from ocean floor subduction/arc formation (ca. 500–438 Ma), ridge subduction (ca. 451–434 Ma) to microcontinent accretion/collision (ca. 430–415 Ma); ridge subduction records the turning point that transformed oceanic lithosphere into continental crust. The recognition of this orogenic cycle followed by Permian–early Triassic terminal collision of the CAOB provides compelling evidence for episodic continental growth.  相似文献   

Revised age of proximal deposits in the Zagros foreland basin and implications for Cenozoic evolution of the High Zagros     

Mohammad D. Fakhari  Gary J. Axen  Brian K. Horton  Jamshid Hassanzadeh  Abdolhossein Amini 《Tectonophysics》2008,451(1-4):170-185

The regionally extensive, coarse-grained Bakhtiyari Formation represents the youngest synorogenic fill in the Zagros foreland basin of Iran. The Bakhtiyari is present throughout the Zagros fold-thrust belt and consists of conglomerate with subordinate sandstone and marl. The formation is up to 3000 m thick and was deposited in foredeep and wedge-top depocenters flanked by fold-thrust structures. Although the Bakhtiyari concordantly overlies Miocene deposits in foreland regions, an angular unconformity above tilted Paleozoic to Miocene rocks is expressed in the hinterland (High Zagros).

The Bakhtiyari Formation has been widely considered to be a regional sheet of Pliocene–Pleistocene conglomerate deposited during and after major late Miocene–Pliocene shortening. It is further believed that rapid fold growth and Bakhtiyari deposition commenced simultaneously across the fold-thrust belt, with limited migration from hinterland (NE) to foreland (SW). Thus, the Bakhtiyari is generally interpreted as an unmistakable time indicator for shortening and surface uplift across the Zagros. However, new structural and stratigraphic data show that the most-proximal Bakhtiyari exposures, in the High Zagros south of Shahr-kord, were deposited during the early Miocene and probably Oligocene. In this locality, a coarse-grained Bakhtiyari succession several hundred meters thick contains gray marl, limestone, and sandstone with diagnostic marine pelecypod, gastropod, coral, and coralline algae fossils. Foraminiferal and palynological species indicate deposition during early Miocene time. However, the lower Miocene marine interval lies in angular unconformity above ~ 150 m of Bakhtiyari conglomerate that, in turn, unconformably caps an Oligocene marine sequence. These relationships attest to syndepositional deformation and suggest that the oldest Bakhtiyari conglomerate could be Oligocene in age.

The new age information constrains the timing of initial foreland-basin development and proximal Bakhtiyari deposition in the Zagros hinterland. These findings reveal that structural evolution of the High Zagros was underway by early Miocene and probably Oligocene time, earlier than commonly envisioned. The age of the Bakhtiyari Formation in the High Zagros contrasts significantly with the Pliocene–Quaternary Bakhtiyari deposits near the modern deformation front, suggesting a long-term (> 20 Myr) advance of deformation toward the foreland.  相似文献   

Potential for localized groundwater contamination in a porous pavement parking lot setting in Rhode Island     

Thomas B. Boving  Mark H. Stolt  Janelle Augenstern  Brian Brosnan 《Environmental Geology》2008,55(3):571-582

The control of polluted surface runoff and the assessment of possible impacts on groundwater is a concern at the local and regional scale. On this background, a study investigates possible impacts of organic and inorganic pollutants (including bacteria) originating from a permeable asphalt parking lot on the water quality immediately beneath it. The functioning of the permeable pavement, including clogging and restricted vertical percolation, was also evaluated. Four nested sample ports (shallow and deep) were installed below low- and high-traffic areas, including one port outside the parking lot. At least initially there was a good hydraulic connection between the parking surface and the shallow sample ports. The presence of a geotextile layer at the base of the parking lot structure, however, was identified in lab tests as one factor restricting vertical percolation to the deeper ports. Clogging of the permeable surface was most pronounced in heavy traffic areas and below snow pile storage areas. Corroborated by high electric conductivity and chloride measurements, sand brought in by cars during winter was the principal cause for clogging. No bacteria or BOD were found in percolating water. Polycyclic aromatic hydrocarbons (PAH) were present at concentrations near minimum detection limit. Nutrients (nitrate and phosphate) were being leached into the ground via the permeable parking lot surface at annual flux rates of 0.45–0.84 g/m²/year. A multi-species tracer test demonstrated a retention capacity of the permeable parking lot structure of >90% for metals and 27% for nutrients, respectively.  相似文献   

The effects of metamorphism on O and Fe isotope compositions in the Biwabik Iron Formation, northern Minnesota   总被引：3，自引：0，他引：3  

Elizabeth Valaas Hyslop  John W. Valley  Clark M. Johnson  Brian L. Beard 《Contributions to Mineralogy and Petrology》2008,155(3):313-328

The Biwabik Iron Formation of Minnesota (1.9 Ga) underwent contact metamorphism by intrusion of the Duluth Complex (1.1 Ga). Apparent quartz–magnetite oxygen isotope temperatures decrease from ∼700°C at the contact to ∼375°C at 2.6 km distance (normal to the contact in 3D). Metamorphic pigeonite at the contact, however, indicates that peak temperatures were greater than 825°C. The apparent O isotope temperatures, therefore, reflect cooling, and not peak metamorphic conditions. Magnetite was reset in δ¹⁸O as a function of grain size, indicating that isotopic exchange was controlled by diffusion of oxygen in magnetite for samples from above the grunerite isograd. Apparent quartz–magnetite O isotope temperatures are similar to calculated closure temperatures for oxygen diffusion in magnetite at a cooling rate of ∼5.6°C/kyr, which suggests that the Biwabik Iron Formation cooled from ∼825 to 400°C in ∼75 kyr at the contact with the Duluth Complex. Isotopic exchange during metamorphism also occurred for Fe, where magnetite–Fe silicate fractionations decrease with increasing metamorphic grade. Correlations between quartz–magnetite O isotope fractionations and magnetite–iron silicate Fe isotope fractionations suggest that both reflect cooling, where the closure temperature for Fe was higher than for O. The net effect of metamorphism on δ¹⁸O–δ⁵⁶Fe variations in magnetite is a strong increase in δ¹⁸O_Mt and a mild decrease in δ⁵⁶Fe with increasing metamorphic grade, relative to the isotopic compositions that are expected at the low temperatures of initial magnetite formation. If metamorphism of Iron Formations occurs in a closed system, bulk O and Fe isotope compositions may be preserved, although re-equilibration among the minerals may occur for both O and Fe isotopes. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Iron isotopes constrain biologic and abiologic processes in banded iron formation genesis   总被引：10，自引：0，他引：10  

Clark M. Johnson  Brian L. Beard  Nic J. Beukes 《Geochimica et cosmochimica acta》2008,72(1):151-169

The voluminous 2.5 Ga banded iron formations (BIFs) from the Hamersley Basin (Australia) and Transvaal Craton (South Africa) record an extensive period of Fe redox cycling. The major Fe-bearing minerals in the Hamersley-Transvaal BIFs, magnetite and siderite, did not form in Fe isotope equilibrium, but instead reflect distinct formation pathways. The near-zero average δ⁵⁶Fe values for magnetite record a strong inheritance from Fe³⁺ oxide/hydroxide precursors that formed in the upper water column through complete or near-complete oxidation. Transformation of the Fe³⁺ oxide/hydroxide precursors to magnetite occurred through several diagenetic processes that produced a range of δ⁵⁶Fe values: (1) addition of marine hydrothermal , (2) complete reduction by bacterial dissimilatory iron reduction (DIR), and (3) interaction with excess that had low δ⁵⁶Fe values and was produced by DIR. Most siderite has slightly negative δ⁵⁶Fe values of ∼ −0.5‰ that indicate equilibrium with Late Archean seawater, although some very negative δ⁵⁶Fe values may record DIR. Support for an important role of DIR in siderite formation in BIFs comes from previously published C isotope data on siderite, which may be explained as a mixture of C from bacterial and seawater sources.Several factors likely contributed to the important role that DIR played in BIF formation, including high rates of ferric oxide/hydroxide formation in the upper water column, delivery of organic carbon produced by photosynthesis, and low clastic input. We infer that DIR-driven Fe redox cycling was much more important at this time than in modern marine systems. The low pyrite contents of magnetite- and siderite-facies BIFs suggests that bacterial sulfate reduction was minor, at least in the environments of BIF formation, and the absence of sulfide was important in preserving magnetite and siderite in the BIFs, minerals that are poorly preserved in the modern marine record. The paucity of negative δ⁵⁶Fe values in older (Early Archean) and younger (Early Proterozoic) BIFs suggests that the extensive 2.5 Ga Hamersley-Transvaal BIFs may record a period of maximum expansion of DIR in Earth’s history.  相似文献   

The effect of species diversity on metal adsorption onto bacteria     

Brian R. Ginn 《Geochimica et cosmochimica acta》2008,72(16):3939-3948

In this study, we measure proton, Pb, and Cd adsorption onto the bacteria Deinococcus radiodurans, Thermus thermophilus, Acidiphlium angustum, Flavobacterium aquatile, and Flavobacterium hibernum, and we calculate the thermodynamic stability constants for the important surface complexes. These bacterial species represent a wide genetic diversity of bacteria, and they occupy a wide range of habitats. All of the species, except for A. angustum, exhibit similar proton and metal uptake. The only species tested that exhibits significantly different protonation behavior is A. angustum, an acidophile that grows at significantly lower pH than the other species of this study. We demonstrate that a single, metal-specific, surface complexation model can be used to reasonably account for the acid/base and metal adsorption behaviors of each species. We use a four discrete site non-electrostatic model to describe the protonation of the bacterial functional groups, with averaged pK_a values of 3.1 ± 0.3, 4.8 ± 0.2, 6.7 ± 0.1, and 9.2 ± 0.3, and site concentrations of (1.0 ± 0.17) × 10⁻⁴, (9.0 ± 3.0) × 10⁻⁵, (4.6 ± 1.8) × 10⁻⁵, and (6.1 ± 2.3) × 10⁻⁵ mol of sites per gram wet mass of bacteria, respectively. Adsorption of Cd and Pb onto the bacteria can be accounted for by the formation of complexes with each of the bacterial surface sites. The average log stability constants for Cd complexes with Sites 1-4 are 2.4 ± 0.4, 3.2 ± 0.1, 4.4 ± 0.1, and 5.3 ± 0.1, respectively. The average log stability constants for Pb complexes with Sites 1-4 are 3.3 ± 0.2, 4.5 ± 0.3, 6.5 ± 0.1, and 7.9 ± 0.5, respectively. This study demonstrates that a wide range of bacteria exhibit similar proton and metal adsorption behaviors, and that a single set of averaged acidity constants, site concentrations, and stability constants for metal-bacterial surface complexes yields a reasonable model for the adsorption behavior of many of these species. The differences in adsorption behavior that we observed for A. angustum demonstrate that genetic differences do exist between the cell wall functional group chemistries of some bacterial species, and that significant exceptions to the typical bacterial adsorption behavior do exist.  相似文献   

Gaseous mercury emissions from urban surfaces: Controls and spatiotemporal trends     

Chris S. Eckley  Brian Branfireun 《Applied Geochemistry》2008

The spatial and temporal variability of Hg emissions from urban paved surfaces was assessed through repeated measurements under varying environmental conditions at six sample sites in Toronto, Ontario, Canada. The results show significant spatial variability of the Hg emissions with median values ranging from below detection limit to 5.2 ng/m²/h. Two of the sites consistently had higher Hg emissions (on several occasions >20 ng/m²/h) than the other 4, which were equivalently low (maximum emission: 2.1 ng/m²/h). A surrogate measure of the pavement Hg concentrations was obtained during each day of sampling through the collection of street dust. The median street dust concentration also showed significant spatial variability (ranging from 9.6 to 44.5 ng/g). Regression analysis showed that the spatial variability of the Hg emissions was significantly related to the street dust concentrations. Controlled experiments using Hg amended street dust confirmed the relationship between Hg surface concentration and emission magnitude. Within a given sample site, Hg emissions varied temporally and multiple regression analysis showed that within-site variability was significantly influenced by changes in solar radiation with only a minor effect from surface temperature. Controlled experiments using shade cloths confirmed that solar radiation can have a large influence on the magnitude of Hg emissions within a given site. The emissions measured in Toronto were contextualized through comparison sampling in Austin, Texas. The Hg emissions measured in Austin were within the range detected in Toronto and also showed significant correlation with Hg street dust concentrations between sites. To provide a holistic assessment of Hg emissions from urban environments, samples were also collected from other common urban surfaces (soil, roofs, and windows). Soils consistently had higher emissions than all the other surfaces (7.3 ng/m²/h, n = 39).  相似文献   

Thermal history of the unsaturated zone at Yucca Mountain,Nevada, USA     

Joseph F. Whelan  Leonid A. Neymark  Richard J. Moscati  Brian D. Marshall  Edwin Roedder 《Applied Geochemistry》2008

Secondary calcite, silica and minor amounts of fluorite deposited in fractures and cavities record the chemistry, temperatures, and timing of past fluid movement in the unsaturated zone at Yucca Mountain, Nevada, the proposed site of a high-level radioactive waste repository. The distribution and geochemistry of these deposits are consistent with low-temperature precipitation from meteoric waters that infiltrated at the surface and percolated down through the unsaturated zone. However, the discovery of fluid inclusions in calcite with homogenization temperatures (T_h) up to ∼80 °C was construed by some scientists as strong evidence for hydrothermal deposition. This paper reports the results of investigations to test the hypothesis of hydrothermal deposition and to determine the temperature and timing of secondary mineral deposition. Mineral precipitation temperatures in the unsaturated zone are estimated from calcite- and fluorite-hosted fluid inclusions and calcite δ¹⁸O values, and depositional timing is constrained by the ²⁰⁷Pb/²³⁵U ages of chalcedony or opal in the deposits. Fluid inclusion T_h from 50 samples of calcite and four samples of fluorite range from ∼35 to ∼90 °C. Calcite δ¹⁸O values range from ∼0 to ∼22‰ (SMOW) but most fall between 12 and 20‰. The highest T_h and the lowest δ¹⁸O values are found in the older calcite. Calcite T_h and δ¹⁸O values indicate that most calcite precipitated from water with δ¹⁸O values between −13 and −7‰, similar to modern meteoric waters.  相似文献